室内空气和灰尘中全(多)氟烷基化合物的研究进展

全(多)氟烷基化合物(per(poly)fluoroalkyl substances,PFASs)在环境各个介质及人体样品中广泛被检出,近年,在室内空气和灰尘中也普遍发现PFASs.研究表明,室内空气中PFASs的含量普遍高于室外空气,室内空气和灰尘中的PFASs可能是室外空气的污染来源及人体暴露源,因此室内环境中PFASs成为环境领域的又一个研究热点.但目前为止,我国还没有开展室内空气中PFASs的相关研究,室内灰尘中PFASs的研究也相对较少.本文就室内空气和灰尘中PFASs的采样与分析方法、污染现状、来源分析及人体暴露等4个方面进行了综合阐述,以期为我国室内环境中PFASs的研究提供参考.     

2013年苏州春季一次重污染天气的过程分析

研究了2013年3月在江苏范围内的一次重污染天气过程，重点分析苏州在此次污染过程中大气污染的变化特征。污染过程中，苏州市颗粒物浓度上升较为明显， PM10的小时质量浓度最高达548μg／m3， PM2．5质量浓度也达到197μg／m3，污染持续时间为2 d，3月8—9日当地空气质量均达到中度污染水平。根据后向轨迹模型、颗粒物离子浓度的分析，此次污染是由外来浮尘及苏州本地污染物排放所造成的区域霾污染影响所致。根据监测结果与实际污染特征，针对性地提出了对策和措施。     

Dust Storms are an Indication of an Unhealthy Environment in East Asia

Dust storms frequently occur in Mongolia and in northern China. Each year there are 30 to 120 dusty days in source regions of Mongolia and 14–20 dusty days on the Korean Peninsula. Intense sand storms and associated dust falls produce environmental impacts in East Asia. This paper discusses the environmental degradation in Mongolia and the social, economic and atmospheric impacts of dust storms in the sink area. The impact of dust storms on environmental compartments as well as their direct and indirect consequences to basic resources like water and energy demand and supply is explained. Governments are encouraged to take appropriate action in specified regions. For monitoring dust storms there is a need for international cooperation to combat growing environmental and human security concerns.     

冲击水浴喷雾式除尘器的应用

介绍了冲击水浴喷雾式除尘器在柳钢焦化厂的应用试验情况，制作安装，调试运行后检测鉴定表明，冲击水浴喷雾式除尘器应用在冶金焦末粉尘上，不但操作简单，维护方便，除尘效率高，效果好，而且成本低廉，只有电除尘器或布袋除尘器的20%左右。     

Methodological Basis of Ecological Safety Standards for the Technogenic Impact of Mineral Resource Exploitation

A new methodological approach to the development of biological and technological safety standards for the impact of underground mining on the natural biota is proposed.     

山东省矿产资源可持续利用面临的困境及解决途径

山东省正处于工业化的中期阶段。矿产资源可持续利用面临重大挑战。本文分析了我国矿业大省——山东省的矿产资源开发利用存在的问题。提出山东省提高矿产资源的保障能力、促进矿产资源可持续利用的对策建议。     

中国经济的“阿基米德支点”

资源是经济发展的“阿基米德支点”：世界十大经济国每年能源的生产占全球的６２．１％，消费为７１．０％。重要矿产资源的生产多排在世界前１０名生产国之，外面是消费则多排在１０名之内，且对这些矿产资源的消费量多在９５％以上。     

我国矿产资源态势与对策

我国矿产资源总量大,居世界第3位人均拥有量小,居世界第80位。我国要实现现代化建设的第二步战略目标,矿产资源供需存在着矛盾。为了解决供需矛盾,必须从地质找矿、矿山、一次资源回收、二次资源回收、节能和节材等方面挖掘潜力。改革资源耗费型经济发展旧模式,确立资源节约型经济发展新模式,废止“有水快流”的方针,确立开发与节约并重的方针,是缓解矿产资源供需矛盾的根本途径。具体对策有:(1)依靠科学技术进步开发节约(2)搞好资源进出口贸易取长补短(3)健全法制管理体系依法治矿(4)用好计划机制管好资源和矿山(5)用好市场机制搞活矿业经济。     

Reactive uptake of NO2 on volcanic particles: A possible source of HONO in the atmosphere

The heterogeneous degradation of nitrogen dioxide (NO₂) on five samples of natural Icelandic volcanic particles has been investigated. Laboratory experiments were carried out under simulated atmospheric conditions using a coated wall flow tube (CWFT). The CWFT reactor was coupled to a blue light nitrogen oxides analyzer (NO_x analyzer), and a long path absorption photometer (LOPAP) to monitor in real time the concentrations of NO₂, NO and HONO, respectively. Under dark and ambient relative humidity conditions, the steady state uptake coefficients of NO₂ varied significantly between the volcanic samples probably due to differences in magma composition and morphological variation related with the density of surface OH groups. The irradiation of the surface with simulated sunlight enhanced the uptake coefficients by a factor of three indicating that photo-induced processes on the surface of the dust occur. Furthermore, the product yields of NO and HONO were determined under both dark and simulated sunlight conditions. The relative humidity was found to influence the distribution of gaseous products, promoting the formation of gaseous HONO. A detailed reaction mechanism is proposed that supports our experimental observations. Regarding the atmospheric implications, our results suggest that the NO₂ degradation on volcanic particles and the corresponding formation of HONO is expected to be significant during volcanic dust storms or after a volcanic eruption.     

Coupling mechanism of activated carbon mixed with dust for flue gas desulfurization and denitrification

To clarify the effect of coking dust, sintering dust and fly ash on the activity of activated carbon for various industrial flue gas desulfurization and denitrification, the coupling mechanism of the mixed activated carbon and dust was investigated to provide theoretical reference for the stable operation. The results show that coking dust had 34% desulfurization efficiency and 10% denitrification efficiency; correspondingly, sintering dust and fly ash had no obvious desulfurization and denitrification activities. For the mixture of activated carbon and dust, the coking dust reduced the desulfurization and denitrification efficiencies by blocking the pores of activated carbon, and its inhibiting effect on activated carbon was larger than its own desulfurization and denitrification activity. The sintering dust also reduced the desulfurization efficiency on the activated carbon while enhancing the denitrification efficiency. Fly ash blocked the pores of activated carbon and reduced its reaction activity. The reaction activity of coking dust mainly came from the surface functional groups, similar to that of activated carbon. The reaction activity of sintering dust mainly came from the oxidative property of Fe₂O₃, which oxidized NO to NO₂ and promoted the fast selectively catalytic reduction (SCR) of NO to form N₂. Sintering dust was activated by the joint action of activated carbon, and both had a coupling function. Sintering dust enhanced the adsorption and oxidation of NO, and activated carbon further promoted the reduction of NO_x by NH₃; thus, the denitrification efficiency increased by 5%-7% on the activated carbon.